[(C6Me6)RuCl2]2
(Hexamethylbenzene)ruthenium(II) Dichloride Dimer
CAS: 67421-02-7
Molecular Formula: C24H36Cl4Ru212*
[(C6Me6)RuCl2]2 - Names and Identifiers
[(C6Me6)RuCl2]2 - Physico-chemical Properties
| Molecular Formula | C24H36Cl4Ru212* |
| Molar Mass | 668.49 |
| Melting Point | >300°C |
| Appearance | powder to crystal |
| Color | Orange to Brown |
| Storage Condition | 2-8°C |
| MDL | MFCD03701102 |
[(C6Me6)RuCl2]2 - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | 20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. |
| Safety Description | 36 - Wear suitable protective clothing. |
| WGK Germany | 3 |
| HS Code | 28439000 |
[(C6Me6)RuCl2]2 - Introduction
Hexamethylbenzene ruthenium(II) dichloride dimer, also known as (Hexamethylbenzene)ruthenium(II) Dichloride Dimer, is a ruthenium-containing organometallic compound. The following is a brief description of its nature, use, preparation and safety information:
Nature:
-Appearance: Hexamethylphenylruthenium (II) dichloride dimer presents a yellow to orange crystal or powdery solid.
-Chemical structure: The chemical formula of this compound is [C6(CH3)6]Ru2Cl4, which consists of a rhenium center and two chloride ions.
-Solubility: Hexamethylphenyl ruthenium (II) dichloride dimer has low solubility in common solvents.
Use:
-Catalyst: Hexamethylbenzene ruthenium (II) dichloride dimer is often used as a catalyst in organic synthesis reactions, especially to catalyze hydrogen transfer reactions, cyclization reactions and olefin activation reactions.
-Redox catalyst: This compound can also be used as an oxygen reduction catalyst in fuel cells.
Preparation Method:
The preparation of hexamethylbenzene ruthenium (II) dichloride dimer usually involves the following steps:
1. Prepare hexamethylbenzene (ruthenocene) and ruthenium (II) dichloride.
2. Mix these two compounds in an appropriate solvent, and perform heat treatment through reaction.
3. The product was filtered and recrystallized to obtain pure hexamethylphenyl ruthenium (II) dichloride dimer.
Safety Information:
-The specific toxicity and danger of hexamethylbenzene ruthenium (II) dichloride dimer have not been fully determined, so care should be taken when using and operating.
-The compound should be kept away from ignition and oxidizing agents, and should be operated in a well-ventilated area.
-In case of contact with skin or eyes, rinse immediately with plenty of water and seek medical help.
-Avoid inhalation or ingestion of the substance during synthesis and handling.
-For specific guidance on use and disposal, please refer to the relevant safety data form or consult a professional.
Nature:
-Appearance: Hexamethylphenylruthenium (II) dichloride dimer presents a yellow to orange crystal or powdery solid.
-Chemical structure: The chemical formula of this compound is [C6(CH3)6]Ru2Cl4, which consists of a rhenium center and two chloride ions.
-Solubility: Hexamethylphenyl ruthenium (II) dichloride dimer has low solubility in common solvents.
Use:
-Catalyst: Hexamethylbenzene ruthenium (II) dichloride dimer is often used as a catalyst in organic synthesis reactions, especially to catalyze hydrogen transfer reactions, cyclization reactions and olefin activation reactions.
-Redox catalyst: This compound can also be used as an oxygen reduction catalyst in fuel cells.
Preparation Method:
The preparation of hexamethylbenzene ruthenium (II) dichloride dimer usually involves the following steps:
1. Prepare hexamethylbenzene (ruthenocene) and ruthenium (II) dichloride.
2. Mix these two compounds in an appropriate solvent, and perform heat treatment through reaction.
3. The product was filtered and recrystallized to obtain pure hexamethylphenyl ruthenium (II) dichloride dimer.
Safety Information:
-The specific toxicity and danger of hexamethylbenzene ruthenium (II) dichloride dimer have not been fully determined, so care should be taken when using and operating.
-The compound should be kept away from ignition and oxidizing agents, and should be operated in a well-ventilated area.
-In case of contact with skin or eyes, rinse immediately with plenty of water and seek medical help.
-Avoid inhalation or ingestion of the substance during synthesis and handling.
-For specific guidance on use and disposal, please refer to the relevant safety data form or consult a professional.
Last Update：2024-04-10 22:29:15
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